Microporous organic polymers based on hexaphenylbiadamantane:synthesis, ultra-high stability and gas capture

Abstract

Hexaphenylbiadamantane-based microporous organic polymers (MOPs) were successfully synthesized by Suzuki coupling under mild conditions. The obtained MOPs show high surface area (891 m2 g−1), ultra-high thermal (less than 40% mass loss at temperatures up to 1000 °C) and chemical (no apparent decomposition in organic solvents for more than 7 days) stability, gas (H2, CO2, CH4) capture capabilities and vapor (benzene, hexane) adsorption. These combined abilities render the synthesized MOPs an attractive candidate as thermo-chemically stable adsorbents for practical use in gas storage and pollutant vapor adsorption.

Publication DOI: https://doi.org/10.1016/j.matlet.2016.10.072
Divisions: College of Engineering & Physical Sciences
College of Engineering & Physical Sciences > Energy and Bioproducts Research Institute (EBRI)
College of Engineering & Physical Sciences > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences > Aston Institute of Materials Research (AIMR)
Additional Information: © 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ Supplementary data available on the journal website.
Uncontrolled Keywords: microporous material,adamantane,stability,adsorption,Materials Science(all),Condensed Matter Physics,Mechanics of Materials,Mechanical Engineering
Full Text Link:
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Article
Published Date: 2017-01-15
Published Online Date: 2016-10-17
Accepted Date: 2016-10-16
Submitted Date: 2016-06-27
Authors: Guo, Jianwei
Lai, Xiangfeng
Fu, Shuqin
Yue, Hangbo
Wang, Jiawei (ORCID Profile 0000-0001-5690-9107)
Topham, Paul D. (ORCID Profile 0000-0003-4152-6976)

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