Production of glucose from the acid hydrolysis of anhydrosugars


Acid hydrolysis of levoglucosan and cellobiose as anhydrosugar model compounds was carried out in an autoclave Parr reaction system, using sulphuric acid as catalyst. In addition, acid hydrolysis was carried out using an anhydrosugars mixture from the aqueous fraction of a pyrolysis oil or bio-oil. The bio-oil was obtained from the fast pyrolysis of birch-wood, and the segregated aqueous fraction was found to contain mainly levoglucosan with a concentration of 30 g L-1. Three main hydrolysis parameters including temperature, reaction time, and catalyst to substrate ratios were varied in order to identify their influence towards glucose production. It was found that at hydrolysis conditions of 120 °C, 60 minutes, and a catalyst/substrate ratio of 0.9; glucose yields of 98.55% and 96.56%, and conversion of substrates of 100% and ~92%, were achieved when hydrolysing cellobiose and levoglucosan respectively. An increase in the hydrolysis temperature from 120 °C to 135 °C, resulted in a decrease in the glucose yield and selectivity. Whereas high conversions of substrates (~90%) were maintained for both anhydrosugars. This was attributed to the further dehydration reactions of glucose, possibly yielding HMF or levulinic acid. During the acid hydrolysis of the bio-oil aqueous fraction, a range of hydrolysis conditions suitable to achieve glucose yields higher than 90%, was depicted. It was found that catalyst/substrate molar ratios between 0.17-0.90 and temperatures between 118 °C and 126 °C were suitable conditions to achieve glucose yields ~100% (30 g L-1). Furthermore, glucose concentrations ~117% (35 g L-1) and levoglucosan conversions above 90%, were attained at 135 °C, 20 minutes reaction time and at an estimated catalyst/substrate molar ratio of 0.2 (H2SO4, 0.5 M).

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Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences
College of Engineering & Physical Sciences > Energy and Bioproducts Research Institute (EBRI)
Additional Information: Copyright © 2018 American Chemical Society
Publication ISSN: 2168-0485
Last Modified: 20 Jun 2024 07:11
Date Deposited: 23 Aug 2018 12:50
Full Text Link:
Related URLs: http://pubs.acs ... chemeng.8b02202 (Publisher URL)
PURE Output Type: Article
Published Date: 2018-10-01
Published Online Date: 2018-08-17
Accepted Date: 2018-08-17
Authors: Blanco, Paula H (ORCID Profile 0000-0002-9456-758X)
Lad, Jai
Bridgwater, Anthony V. (ORCID Profile 0000-0001-7362-6205)
Holm, Martin S.



Version: Accepted Version

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