Potassium-modified bifunctional MgAl-SBA-15 for aldol condensation of furfural and acetone


The aldol condensation of furfural and acetone followed by hydrodeoxygenation into bio-jet fuel range alkanes and bio-polyester diols has attracted intensive interest in recent years. Such sequential reactions require a careful tailoring of one or more catalysts consisting of metal and acid–base active sites that can efficiently promote the two step cascade aldol condensation and hydrodeoxygenation. Here, we have begun developing a prominent base catalyst for mild aldol condensation of furfural and acetone by synthesizing acid–base bifunctional MgAl-SBA-15 and further modifying it with potassium. The catalyst with the highest basic site loading of 0.27 mmol g−1 showed a furfural conversion of 83% and 99% total selectivity to products comprising 54% 4-(2-furyl)-4-hydroxy-butan-2-one (FAc-OH, a C8 alcohol intermediate) and 23% of each 4-(2-furyl)-3-buten-2-one (FAc) and 1,4-pentadiene-3-one,1,5-di-2-furanyl (F2Ac) (C8 and C13 aldol condensation products, respectively) after 3 hours of reaction, at 50 °C. Though a higher loading of potassium causes severe blockages of mesopores and inaccessible acid sites, the catalyst could still be regenerated by open-air calcination and be re-used for considerable cycles with fair catalytic performances. Overall, the present study can be the stepping stone for future investigations on further tuning of non-interfering active sites in SBA-15 to promote an efficient one-pot transformation of furfural and acetone via the two-step cascade aldol condensation and hydrodeoxygenation.

Publication DOI: https://doi.org/10.1039/D3SE00444A
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences
College of Engineering & Physical Sciences > Energy and Bioproducts Research Institute (EBRI)
Additional Information: Funding: The authors thank European Structural and Investment Funds, OP RDE-funded project ‘ChemJets2’ (CZ.02.2.69/0.0/0.0/18_053/0016974) for its financial support. Mahashanon Arumugam and Amin Osatiashtiani would like to thank Aston University for the International Visiting Scholar Fund. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Publication ISSN: 2398-4902
Full Text Link:
Related URLs: https://pubs.rs ... 3/SE/D3SE00444A (Publisher URL)
PURE Output Type: Article
Published Date: 2023-05-31
Accepted Date: 2023-05-11
Authors: Arumugam, Mahashanon
Kikhtyanin, Oleg
Osatiashtiani, Amin (ORCID Profile 0000-0003-1334-127X)
Kyselová, Veronika
Fila, Vlastimil
Paterova, Iva
Wong, Ka-Lun
Kubička, David



Version: Published Version

License: Creative Commons Attribution

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