Nuclear-driven production of renewable fuel additives from waste organics


Non-intermittent, low-carbon energy from nuclear or biofuels is integral to many strategies to achieve Carbon Budget Reduction targets. However, nuclear plants have high, upfront costs and biodiesel manufacture produces waste glycerol with few secondary uses. Combining these technologies, to precipitate valuable feedstocks from waste glycerol using ionizing radiation, could diversify nuclear energy use whilst valorizing biodiesel waste. Here, we demonstrate solketal (2,2-dimethyl-1,3-dioxolane-4-yl) and acetol (1-hydroxypropan-2-one) production is enhanced in selected aqueous glycerol-acetone mixtures with γ radiation with yields of 1.5 ± 0.2 µmol J−1 and 1.8 ± 0.2 µmol J−1, respectively. This is consistent with the generation of either the stabilized, protonated glycerol cation (CH2OH-CHOH-CH2OH2+ ) from the direct action of glycerol, or the hydronium species, H3O+, via water radiolysis, and their role in the subsequent acid-catalyzed mechanisms for acetol and solketal production. Scaled to a hypothetically compatible range of nuclear facilities in Europe (i.e., contemporary Pressurised Water Reactor designs or spent nuclear fuel stores), we estimate annual solketal production at approximately (1.0 ± 0.1) × 104 t year−1. Given a forecast increase of 5% to 20% v/v% in the renewable proportion of commercial petroleum blends by 2030, nuclear-driven, biomass-derived solketal could contribute towards net-zero emissions targets, combining low-carbon co-generation and co-production.

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Divisions: College of Engineering & Physical Sciences
College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
Additional Information: This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit Funding: The authors (B.K., L.S.) acknowledge the financial support from the Slovenian Research Agency (research core funding No. (P2-0073). The authors (A.J., L.S.) acknowledge the financial support from the Slovenian Research Agency (research infrastructure core funding TRIGA Mark II research reactor). M.J.J. acknowledges the support of the Royal Society via a Wolfson Research Merit Award.
Uncontrolled Keywords: Biochemistry,Chemistry(all),Environmental Chemistry,Materials Chemistry
Publication ISSN: 2399-3669
Last Modified: 23 Apr 2024 07:24
Date Deposited: 20 Sep 2021 07:38
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Related URLs: https://www.nat ... 004-021-00572-5 (Publisher URL)
http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Article
Published Date: 2021-09-17
Accepted Date: 2021-08-26
Submitted Date: 2021-04-26
Authors: Plant, Arran George
Kos, Bor
Jazbec, Anže
Snoj, Luka
Najdanovic-Visak, Vesna (ORCID Profile 0000-0002-1035-0982)
Joyce, Malcolm John



Version: Published Version

License: Creative Commons Attribution

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