Integrating Pd-doped perovskite catalysts with ceramic hollow fibre substrate for efficient CO oxidation

Abstract

Doping Pd into perovskite catalysts helps to reduce light-off temperatures, improve thermal-chemical stability and lowered catalyst cost by decreasing Platinum Group Metals (PGMs). In this study, LaFe0.7Mn0.225Pd0.075O3 (LFMPO) and LaFe0.7Co0.225Pd0.075O3 (LFCPO) were synthesised, characterized and evaluated for catalytic treatment of automotive emissions, using CO oxidation as the model reaction. Such catalysts were further incorporated inside micro-structured ceramic hollow fibre substrates, and compared with a packed bed configuration by light-off temperatures. Performance evaluations suggest that, LFMPO deposited inside the hollow fibre substrate could be light up at 232 °C, which is 10 °C lower than a packed-bed counterpart with the same amount of catalyst (5 mg) and GHSV of ∼5300 h−1. While excessive incorporation of the catalyst (10 mg) generates significantly higher transfer resistance, which impairs catalytic performance of hollow fibre reactors, with CO conversion per gram of catalyst reduced from 0.01 mol g−1 to 0.0051 mol g−1.

Publication DOI: https://doi.org/10.1016/j.jece.2020.103897
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
Additional Information: © 2020, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ Funding: The authors would like to acknowledge the research funding provided by EPSRC (EP/R029180/1) in the United Kingdom.
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Related URLs: https://linking ... 213343720302451 (Publisher URL)
PURE Output Type: Article
Published Date: 2020-08-01
Published Online Date: 2020-04-28
Accepted Date: 2020-03-24
Authors: Mahyon, Nur Izwanne
Li, Tao
Tantra, Billy Digjaya
Martinez-botas, Ricardo
Wu, Zhentao (ORCID Profile 0000-0002-4934-8046)
Li, Kang

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