Layer-by-layer deposition of open-pore mesoporous TiO 2- Nafion® film electrodes


The formation of variable thickness TiO2 nanoparticle-Nafion® composite films with open pores is demonstrated via a layer-by-layer deposition process. Films of about 6 nm diameter TiO2 nanoparticles grow in the presence of Nafion® by “clustering” of nanoparticles into bigger aggregates, and the resulting hierarchical structure thickens with about 25 nm per deposition cycle. Film growth is characterized by electron microscopy, atomic force microscopy, and quartz crystal microbalance techniques. Simultaneous small-angle X-ray scattering and wide-angle X-ray scattering measurements for films before and after calcination demonstrate the effect of Nafion® binder causing aggregation. Electrochemical methods are employed to characterize the electrical conductivity and diffusivity of charge through the TiO2-Nafion® composite films. Characteristic electrochemical responses are observed for cationic redox systems (diheptylviologen2+/+, Ru(NH3)3+/2+6, and ferrocenylmethyl-trimethylammonium2+/+) immobilized into the TiO2-Nafion® nanocomposite material. Charge conduction is dependent on the type of redox system and is proposed to occur either via direct conduction through the TiO2 backbone (at sufficiently negative potentials) or via redox-center-based diffusion/electron hopping (at more positive potentials).

Publication DOI:
Divisions: College of Health & Life Sciences > School of Psychology
Additional Information: © Springer Nature B.V. 2007. The final publication is available at Springer via
Publication ISSN: 1433-0768
Last Modified: 01 Jan 2024 08:13
Date Deposited: 21 May 2020 07:30
Full Text Link: http://www.scop ... tnerID=MN8TOARS
Related URLs: https://link.sp ... 0008-006-0247-3 (Publisher URL)
PURE Output Type: Article
Published Date: 2007
Authors: Milsom, E.V.
Novak, J. (ORCID Profile 0000-0001-5173-3608)
Green, S.J.
Zhang, Xiaohang
Stott, S.J.
Mortimer, R.J.
Edler, K.
Marken, F.



Version: Accepted Version

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