Effects of separation layer thickness on oxygen permeation and mechanical strength of DL-HFMR-ScSZ


It has been demonstrated in our previous studies that in order for greater methane conversion and less coke-formation, a higher oxygen permeation rate through the outer oxygen separation layer of a functional dual-layer ceramic hollow fibre membrane is needed. Besides new membrane materials with higher oxygen permeability, another way of improving oxygen permeation is to reduce the separation layer thickness, although this strategy is limited by the characteristic thickness, L c, where bulk diffusion and surface oxygen exchange are both important. As a result, a series of La 0.80Sr 0.20MnO 3-δ (LSM)-Scandia(10%)-Stabilized-Zirconia (ScSZ)/ScSZ-NiO functional dual-layer hollow fibres (DL-HF) with an outer oxygen separation layer thickness between approximately 8.0 and 72.4μm were fabricated in this study, by using the single-step co-extrusion and co-sintering process. The effects of separation layer thickness on oxygen permeation and mechanical strength were investigated. The oxygen permeation of the LSM-ScSZ separation layer is more likely to be controlled by surface exchange at higher temperatures, and changes to mixed control by both bulk diffusion and surface exchange at lower temperatures. A thicker separation layer also results in a thinner catalytic substrate layer, and subsequently decreases the mechanical strength of the dual-layer hollow fibre membrane.

Publication DOI: https://doi.org/10.1016/j.memsci.2012.05.003
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
Funding Information: The authors would like to acknowledge the EPSRC (grant no: EP/G012679/1 ) for financial support.
Additional Information: © 2012, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Uncontrolled Keywords: Co-extrusion and co-sintering,Dual-layer ceramic hollow fibre,Membrane reactor,Methane conversion,Oxygen permeation,Biochemistry,Materials Science(all),Physical and Theoretical Chemistry,Filtration and Separation
Publication ISSN: 1873-3123
Last Modified: 08 Jan 2024 09:24
Date Deposited: 07 Jan 2020 16:25
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Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
https://www.sci ... 3675?via%3Dihub (Publisher URL)
PURE Output Type: Article
Published Date: 2012-10-01
Authors: Wu, Zhentao (ORCID Profile 0000-0002-4934-8046)
Thursfield, Alan
Metcalfe, Ian
Li, K.

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