Correlation of liquid-liquid equilibria of non-ideal binary systems using the non-random, two-liquid model

Abstract

The non-random, two-liquid (NRTL) model with three different forms of temperature dependant parameters was used to correlate the liquid- -liquid equilibrium data for systems of alcohols with alkanes, and alcohols with two ionic liquids: 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim][BF4]) and 1-butyl-3-ethylimidazolium tetrafluoroborate ([beim][BF4]). Different temperature dependences of the NRTL parameters were tested on thirteen literature experimental liquid-liquid equilibrium data for binary systems.

Publication DOI: https://doi.org/10.2298/JSC121002012G
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences
Additional Information: Creative Commons Attribution Non-Commercial No-Derivative Works 3.0 License
Uncontrolled Keywords: Ionic liquids,Liquid - liquid equilibria,Modeling,NRTL model,Optimization,Chemistry(all)
Publication ISSN: 1820-7421
Full Text Link:
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
http://www.dois ... 2G#.Xeoch9X7RhF (Publisher URL)
PURE Output Type: Article
Published Date: 2013-07-15
Authors: Grozdanic, Nikola D.
Kijevcanin, Mirjana L.
Višak, Zoran P. (ORCID Profile 0000-0003-0962-8710)
Grozdanic, Dušan K.
Šerbanovic, Slobodan P.

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