Gupta, Rajender Pershad (1976). Some aspects of the chemistry of sulphinyl and related compounds. PHD thesis, Aston University.
Abstract
β-Ketosulphinyl chlorides have been prepared by the reaction of isopropyl ketones with thionyl chloride and an attempt has also been made to determine the reaction mechanism from the kinetic data. These compounds show a diastereotopic effect of the gem-dimethyl group or suitably positioned hydrogen atoms. This diastereotapic effect is shown to be due to both intrinsic asymmetry and conformational preferences. β-Ketosulphinyl chlorides undergo cleavage of the carbon-sulphur bond on treatment with certain nucleophiles containing oxygen as the nucleophilic atom...
| Publication DOI: | https://doi.org/10.48780/publications.aston.ac.uk.00040635 |
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| Divisions: | College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry |
| Additional Information: | Copyright © RAJENDER PERSHAD GUPTA, 1976. RAJENDER PERSHAD GUPTA asserts their moral right to be identified as the author of this thesis. This copy of the thesis has been supplied on condition that anyone who consults it is understood to recognise that its copyright rests with its author and that no quotation from the thesis and no information derived from it may be published without appropriate permission or acknowledgement. If you have discovered material in Aston Publications Explorer which is unlawful e.g. breaches copyright, (either yours or that of a third party) or any other law, including but not limited to those relating to patent, trademark, confidentiality, data protection, obscenity, defamation, libel, then please read our Takedown Policy and contact the service immediately. |
| Institution: | Aston University |
| Last Modified: | 18 Feb 2025 11:27 |
| Date Deposited: | 28 Oct 2019 15:38 |
| Completed Date: | 1976-09 |
| Authors: |
Gupta, Rajender Pershad
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CORE (COnnecting REpositories)
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