Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible matrix:a vanishing surfactant


The addition of co-solutes to aid the separation of signals from molecules of similar size in DOSY experiments – matrix-assisted DOSY – is a potentially powerful technique for mixture analysis. The additional signals introduced by a co-solute can however greatly complicate analysis. By suitable choice of sample conditions, the NMR peaks of a surfactant matrix can be suppressed, allowing the clear resolution of molecular species according to chemistry and structure, without extraneous interference.

Publication DOI:
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences > Aston Institute of Materials Research (AIMR)
Additional Information: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Funding: EPSRC (EP/E05899X/1 and EP/H024336/1); Givaudan Flavors Division; Mexican Scientic and Technology Council (CONACyT); and SciencewithoutBorders–Brazil(CNPqreferencenumber233163/2014-0 Electronic supplementary information (ESI) available. See DOI: 10.1039/c6ra26144b
Uncontrolled Keywords: Chemistry(all),Chemical Engineering(all)
Publication ISSN: 2046-2069
Full Text Link:
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Article
Published Date: 2017-01-03
Accepted Date: 2016-11-22
Submitted Date: 2016-11-01
Authors: Evans, Robert (ORCID Profile 0000-0003-1471-201X)
Hernandez-Cid, Aaron
dal Poggetto, Guilherme
Vesty, Ashley
Haiber, Stephan
Morris, Gareth A.
Nilsson, Mathias



Version: Published Version

License: Creative Commons Attribution

| Preview

Export / Share Citation


Additional statistics for this record