Matrix-assisted diffusion-ordered spectroscopy


Diffusion NMR is a potentially routine tool in the analysis of mixtures, from industrial and synthetic outputs to natural products. However, the technique struggles to resolve species of similar size. Matrix-assisted DOSY offers a flexible approach to resolving such ambiguities on the basis of the chemical structures involved and on their interactions with a larger co-solute or matrix. The use of chromatographic supports, surfactants and polymers, in particular, is illustrated. The resolution of a wide range of different analyte mixtures, on the basis of differences in chemical structure and in stereochemistry, is demonstrated.

Publication DOI:
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences > Aston Institute of Materials Research (AIMR)
Additional Information: Funding: EPSRC (EP/H025367/1)
Uncontrolled Keywords: Chemical Engineering(all),Chemistry(all)
Publication ISSN: 2046-2069
Full Text Link: http://pubs.rsc ... 0G#!divAbstract
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Review article
Published Date: 2016
Published Online Date: 2016-04-26
Accepted Date: 2016-04-25
Submitted Date: 2016-02-29
Authors: Evans, Robert (ORCID Profile 0000-0003-1471-201X)
Day, Iain J.



Version: Accepted Version

| Preview

Export / Share Citation


Additional statistics for this record