Evans, Robert and Day, Iain J. (2016). Matrix-assisted diffusion-ordered spectroscopy. RSC advances, 6 (52), pp. 47010-47022.
Abstract
Diffusion NMR is a potentially routine tool in the analysis of mixtures, from industrial and synthetic outputs to natural products. However, the technique struggles to resolve species of similar size. Matrix-assisted DOSY offers a flexible approach to resolving such ambiguities on the basis of the chemical structures involved and on their interactions with a larger co-solute or matrix. The use of chromatographic supports, surfactants and polymers, in particular, is illustrated. The resolution of a wide range of different analyte mixtures, on the basis of differences in chemical structure and in stereochemistry, is demonstrated.
Publication DOI: | https://doi.org/10.1039/c6ra05380g |
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Divisions: | College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry College of Engineering & Physical Sciences > Aston Institute of Materials Research (AIMR) |
Additional Information: | Funding: EPSRC (EP/H025367/1) |
Uncontrolled Keywords: | General Chemical Engineering,General Chemistry |
Publication ISSN: | 2046-2069 |
Last Modified: | 02 Dec 2024 08:17 |
Date Deposited: | 19 Aug 2019 10:08 |
Full Text Link: |
http://pubs.rsc ... 0G#!divAbstract |
Related URLs: |
http://www.scop ... tnerID=8YFLogxK
(Scopus URL) |
PURE Output Type: | Review article |
Published Date: | 2016 |
Published Online Date: | 2016-04-26 |
Accepted Date: | 2016-04-25 |
Submitted Date: | 2016-02-29 |
Authors: |
Evans, Robert
(
0000-0003-1471-201X)
Day, Iain J. |