A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials


The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I 8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex. This journal is

Publication DOI: https://doi.org/10.1039/c3dt53126k
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences > Aston Institute of Materials Research (AIMR)
Additional Information: © The Royal Society of Chemistry 2014 Funding: Marie Curie Intra-European Fellowship (project “PolyMoRe”, no. 327440) and the Russian Foundation for Basic Research (Grants nos. 12-03- 31670 and 14-04-01816). Supplementary information available online on the journal pages.
Uncontrolled Keywords: Inorganic Chemistry
Publication ISSN: 1477-9234
Full Text Link: https://hydra.h ... rces/hull:11414
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Article
Published Date: 2014-04-28
Published Online Date: 2014-01-17
Authors: Efremova, O.A.
Shestapalov, M.A.
Chirtsova, N.A.
Smolentsev, A.I.
Mironov, Y.V.
Kitamura, N.
Brylev, K.A.
Sutherland, Andy (ORCID Profile 0000-0003-3651-1809)



Version: Accepted Version

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