Functionalized Periodic Mesoporous Organosilicas: Tunable Hydrophobic Solid Acids for Biomass Conversion


The catalytic deoxygenation of bio-based feedstocks to fuels and chemicals presents new challenges to the catalytic scientist, with many transformations either performed in or liberating water as a byproduct during reaction. The design of catalysts with tunable hydrophobicity to aid product and reactant adsorption or desorption, respectively, is vital for processes including (trans)esterification and condensation reactions employed in sustainable biodiesel production and bio-oil upgrading processes. Increasing surface hydrophobicity of catalyst materials offers a means to displace water from the catalyst active site, and minimizes potential deactivation or hydrolysis side reactions. Hybrid organic–inorganic porous solids offer exciting opportunities to tune surface polarity and hydrophobicity, as well as critical parameters in controlling adsorption, reactant activation, and product selectivity in liquid and vapor phase catalysis. Here, we review advances in the synthesis and application of sulfonic-acid-functionalized periodic mesoporous organosilicas (PMO) as tunable hydrophobic solid acid catalysts in reactions relevant to biorefining and biofuel production.

Publication DOI:
Divisions: College of Engineering & Physical Sciences
Additional Information: © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (
Uncontrolled Keywords: Biofuels,Biorefining,Hydrophobicity,Periodic mesoporous organosilica,Solid acid catalysis,Analytical Chemistry,Chemistry (miscellaneous),Molecular Medicine,Pharmaceutical Science,Drug Discovery,Physical and Theoretical Chemistry,Organic Chemistry
Publication ISSN: 1420-3049
Last Modified: 18 Jun 2024 07:20
Date Deposited: 25 Jan 2019 10:27
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Related URLs: http://www.mdpi ... 0-3049/24/2/239 (Publisher URL)
http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Review article
Published Date: 2019-01-10
Accepted Date: 2019-01-04
Authors: Manayil, Jinesh (ORCID Profile 0000-0002-9864-3332)
Lee, Adam
Wilson, Karen



Version: Published Version

License: Creative Commons Attribution

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