Chiral and chemical oscillations in a simple dimerization model

Abstract

We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.

Publication DOI: https://doi.org/10.1039/c2cp42620j
Divisions: College of Engineering & Physical Sciences > Systems analytics research institute (SARI)
Additional Information: © The Royal Society of Chemistry 2012
Uncontrolled Keywords: Physical and Theoretical Chemistry,Physics and Astronomy(all)
Publication ISSN: 1463-9084
Last Modified: 18 Mar 2024 08:18
Date Deposited: 04 Jun 2018 10:30
Full Text Link:
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Article
Published Date: 2013-01-07
Published Online Date: 2012-09-19
Accepted Date: 2012-09-18
Submitted Date: 2012-07-30
Authors: Stich, Michael (ORCID Profile 0000-0001-8862-1044)
Blanco, Celia
Hochberg, David

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