Karthikeyan, S., Pachamuthu, M.P., Isaacs, Mark A., Kumar, Santosh, Lee, Adam F. and Sekaran, G. (2016). Cu and Fe oxides dispersed on SBA-15:a Fenton type bimetallic catalyst for N,N-diethyl-p-phenyl diamine degradation. Applied Catalysis B, 199 , pp. 323-330.
Abstract
A bimetallic oxidation catalyst has been synthesized via wet impregnation of copper and iron over a mesoporous SBA-15 silica support. Physicochemical properties of the resulting material were characterized by XRD, N2 physisorption, DRUVS, FTIR, Raman, SEM and HRTEM, revealing the structural integrity of the parent SBA-15, and presence of highly dispersed Cu and Fe species present as CuO and Fe2O3. The CuFe/SBA-15 bimetallic catalyst was subsequently utilized for the oxidative degradation of N,N-diethyl-p-phenyl diamine (DPD) employing a H2O2 oxidant in aqueous solution.
Publication DOI: | https://doi.org/10.1016/j.apcatb.2016.06.040 |
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Dataset DOI: | https://doi.org/10.17036/e2817e80-7bbf-4397-81fd-52302e2bd35f |
Divisions: | College of Engineering & Physical Sciences College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry College of Engineering & Physical Sciences > Energy and Bioproducts Research Institute (EBRI) |
Additional Information: | © 2016. The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). Funder information: One of the authors (S.K) acknowledges CSIR, India (grant number 31/6(365)/2012-EMR-I) for Senior Research Fellowship. The financial assistance under STRAIT (CSC0201) network programme to carry out this work is highly acknowledged. A.F.L. thanks the EPSRC for financial support (EP/K021796/1, EP/K029525/2). |
Uncontrolled Keywords: | CuO ,Fe2O3 ,SBA-15 ,Fenton oxidation ,N,N’-diethyl-p-phenyl diamine,Catalysis,Process Chemistry and Technology,General Environmental Science |
Publication ISSN: | 1873-3883 |
Last Modified: | 02 Dec 2024 08:17 |
Date Deposited: | 29 Jun 2016 07:10 |
Full Text Link: | |
Related URLs: |
http://www.scop ... tnerID=8YFLogxK
(Scopus URL) |
PURE Output Type: | Article |
Published Date: | 2016-12-15 |
Published Online Date: | 2016-06-19 |
Accepted Date: | 2016-06-18 |
Submitted Date: | 2016-03-10 |
Authors: |
Karthikeyan, S.
Pachamuthu, M.P. Isaacs, Mark A. Kumar, Santosh ( 0000-0002-1352-9945) Lee, Adam F. ( 0000-0002-2153-1391) Sekaran, G. |