Hunns, James A., Arroyo, Marta, Lee, Adam F., Escola, José M., Serrano, David and Wilson, Karen (2016). Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane. Catalysis Science and Technology, 6 (8), pp. 2560-2564.
Abstract
Mesopore incorporation into ZSM-5 enhances the dispersion of Pd nanoparticles throughout the hierarchical framework, significantly accelerating m-cresol conversion relative to a conventional microporous ZSM-5, and dramatically increasing selectivity towards the desired methylcyclohexane deoxygenated product. Increasing the acid site density further promotes m-cresol conversion and methylcyclohexane selectivity through efficient dehydration of the intermediate methylcyclohexanol.
Publication DOI: | https://doi.org/10.1039/c5cy02072g |
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Dataset DOI: | https://doi.org/10.17036/69310f3c-071f-433b-8c6a-7a5b4b37783e |
Divisions: | College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry College of Engineering & Physical Sciences > Energy and Bioproducts Research Institute (EBRI) |
Additional Information: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Funding: EPSRC (EP/K036548/1 and EP/K014706/1), EU FP7 (FP7/2007-2013) grant agreement 604307 Electronic supplementary information: Full synthetic, characterisation and reaction details. See DOI:10.1039/c5cy02072g |
Uncontrolled Keywords: | Catalysis |
Publication ISSN: | 2044-4761 |
Last Modified: | 02 Dec 2024 08:16 |
Date Deposited: | 31 May 2016 14:40 |
Full Text Link: |
http://pubs.rsc ... 6/CY/C5CY02072G |
Related URLs: |
http://www.scop ... tnerID=8YFLogxK
(Scopus URL) |
PURE Output Type: | Article |
Published Date: | 2016-04-21 |
Published Online Date: | 2015-12-29 |
Accepted Date: | 2015-12-28 |
Submitted Date: | 2015-11-30 |
Authors: |
Hunns, James A.
Arroyo, Marta Lee, Adam F. ( 0000-0002-2153-1391) Escola, José M. Serrano, David Wilson, Karen ( 0000-0003-4873-708X) |