Stabilization of catalyst particles against sintering on oxide supports with high oxygen ion lability exemplified by Ir-catalyzed decomposition of N2O


Iridium nanoparticles deposited on a variety of surfaces exhibited thermal sintering characteristics that were very strongly correlated with the lability of lattice oxygen in the supporting oxide materials. Specifically, the higher the lability of oxygen ions in the support, the greater the resistance of the nanoparticles to sintering in an oxidative environment. Thus with γ-Al2O3 as the support, rapid and extensive sintering occurred. In striking contrast, when supported on gadolinia-ceria and alumina-ceria-zirconia composite, the Ir nanoparticles underwent negligible sintering. In keeping with this trend, the behavior found with yttria-stabilized zirconia was an intermediate between the two extremes. This resistance, or lack of resistance, to sintering is considered in terms of oxygen spillover from support to nanoparticles and discussed with respect to the alternative mechanisms of Ostwald ripening versus nanoparticle diffusion. Activity towards the decomposition of N2O, a reaction that displays pronounced sensitivity to catalyst particle size (large particles more active than small particles), was used to confirm that catalytic behavior was consistent with the independently measured sintering characteristics. It was found that the nanoparticle active phase was Ir oxide, which is metallic, possibly present as a capping layer. Moreover, observed turnover frequencies indicated that catalyst-support interactions were important in the cases of the sinter-resistant systems, an effect that may itself be linked to the phenomena that gave rise to materials with a strong resistance to nanoparticle sintering.

Publication DOI:
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
College of Engineering & Physical Sciences
College of Engineering & Physical Sciences > Energy and Bioproducts Research Institute (EBRI)
Additional Information: © 2016 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license( Funding: EPSRC
Uncontrolled Keywords: sintering,nanoparticle stabilization ,oxide supports ,oxygen ion lability ,Ostwald ripening ,particle diffusion,Catalysis,Process Chemistry and Technology,Environmental Science(all)
Publication ISSN: 1873-3883
Last Modified: 17 Jun 2024 07:19
Date Deposited: 14 Apr 2016 08:20
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Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
PURE Output Type: Article
Published Date: 2016-09-05
Published Online Date: 2016-04-07
Accepted Date: 2016-04-06
Submitted Date: 2016-01-11
Authors: Yentekakis, Ioannis V.
Goula, Grammatiki
Panagiotopoulou, Paraskevi
Kampouri, Stavroula
Taylor, Martin
Kyriakou, Georgios
Lambert, Richard M.



Version: Published Version

License: Creative Commons Attribution

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