Majeed, Z. (1996). New Aspects in Organotellurium Halide Chemistry. Masters thesis, Aston University.
Abstract
A literature review of the known chemistry of organotellurium fluorides and iodides is presented. The synthesises of new organotellurium iodides (RTel and RTel3), where R = 2-(2- pyridyl)phenyl- and 2-phenylazophenyl- have been reported. It is suggested on the basis of spectroscopic examination (NMR, Mass and Raman) that the oxidation state of tellurium in these “tri-iodides” species is (II). Attempts to synthesise RTeF and RTeF; (R = 2-(2-pyridyl)phenyl- and 2- phenylazophenyl-) are reported. The NUR (19F and 125Te) and analytical data for these materials are reported and discussed. A second crystalline modification (monoclinic) form of 2-(phenylazophenyl- C.N’)tellurium(II) chloride, has been formed by recrystallisation from methanol. One molecule is present in the unit cell...
| Publication DOI: | https://doi.org/10.48780/publications.aston.ac.uk.00021743 |
|---|---|
| Divisions: | College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry |
| Additional Information: | Copyright © Z. Majeed, 1996. Z. Majeed asserts their moral right to be identified as the author of this thesis. This copy of the thesis has been supplied on condition that anyone who consults it is understood to recognise that its copyright rests with its author and that no quotation from the thesis and no information derived from it may be published without appropriate permission or acknowledgement. If you have discovered material in Aston Publications Explorer which is unlawful e.g. breaches copyright, (either yours or that of a third party) or any other law, including but not limited to those relating to patent, trademark, confidentiality, data protection, obscenity, defamation, libel, then please read our Takedown Policy and contact the service immediately. |
| Institution: | Aston University |
| Uncontrolled Keywords: | organotellurium halide chemistry |
| Last Modified: | 11 Apr 2025 15:06 |
| Date Deposited: | 19 Mar 2014 17:30 |
| Completed Date: | 1996-05 |
| Authors: |
Majeed, Z.
|
![[img]](https://publications.aston.ac.uk/style/images/fileicons/text.png)