Peterson, W.J. (1975). A Study of the Reactions Between Halides of Metalloids and Phenylacetylenes. Masters thesis, Aston University.
Abstract
The uncatalysed reactions of phenylacetylenes with arsenic trichloride have been shown to give 1:1 trans~additon products whilst the acetylenic acids and their esters give complex cyclic adducts. The reactions provide a novel route to compounds like B-chloro-(p-methylstyryl)diphenylarsine, cis-(p-styryl)diphenylarsine and p-chloro-(p-chlorostyryl)dichloroarsine and in all tvelve novel organo-arsenic compounds have been prepared. The stereochemistry of the 1:1 trans-adducts and their derivatives have been established and an attempt has also been made to determine the reaction mechanism from spectroscopically obtained kinetic data.
| Publication DOI: | https://doi.org/10.48780/publications.aston.ac.uk.00021547 |
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| Divisions: | College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry |
| Additional Information: | Copyright © WINSTON J. PETERSON, 1975. WINSTON J. PETERSON asserts their moral right to be identified as the author of this thesis. This copy of the thesis has been supplied on condition that anyone who consults it is understood to recognise that its copyright rests with its author and that no quotation from the thesis and no information derived from it may be published without appropriate permission or acknowledgement. If you have discovered material in Aston Publications Explorer which is unlawful e.g. breaches copyright, (either yours or that of a third party) or any other law, including but not limited to those relating to patent, trademark, confidentiality, data protection, obscenity, defamation, libel, then please read our Takedown Policy and contact the service immediately. |
| Institution: | Aston University |
| Uncontrolled Keywords: | halides,metalloids,phenylacetylenes |
| Last Modified: | 22 Jan 2025 17:06 |
| Date Deposited: | 19 Mar 2014 12:10 |
| Completed Date: | 1975-01 |
| Authors: |
Peterson, W.J.
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