Pathirana, Hema M.K.K. (1985). Ligand Chemistry of Tellurium. PHD thesis, Aston University.
Abstract
Potentially bidentate tellurium ligands having the molecular formula ArTe(CH2) nTeAr, (Ln), n=1, 5, 6, 7, 9, 10 and o-C6H4,(CH2TeAr) , (L) are prepared by reacting ArTeNa with 1, n-dibromoalkanes or with o-C6H4(CH2Br)2. Changing the reactant ratio from 2:1 to 1:2 resulted In a telluronium salt only in the case of 1,5-dibromopentane. The bromination of some of the bis-tellurides resulted in bis-tribromidesdue to the rupture of the tellurium-aryl bond. The 13C N.M.R. spectra are particularly useful in characterisation of these ligands...
| Publication DOI: | https://doi.org/10.48780/publications.aston.ac.uk.00014516 |
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| Divisions: | College of Health & Life Sciences |
| Additional Information: | Copyright © Hema M.K.K. Pathirana, 1985. Hema M.K.K. Pathirana asserts their moral right to be identified as the author of this thesis. This copy of the thesis has been supplied on condition that anyone who consults it is understood to recognise that its copyright rests with its author and that no quotation from the thesis and no information derived from it may be published without appropriate permission or acknowledgement. If you have discovered material in Aston Publications Explorer which is unlawful e.g. breaches copyright, (either yours or that of a third party) or any other law, including but not limited to those relating to patent, trademark, confidentiality, data protection, obscenity, defamation, libel, then please read our Takedown Policy and contact the service immediately. |
| Institution: | Aston University |
| Uncontrolled Keywords: | ligand chemistry,tellurium |
| Last Modified: | 02 Apr 2025 13:40 |
| Date Deposited: | 22 Feb 2011 11:20 |
| Completed Date: | 1985-10 |
| Authors: |
Pathirana, Hema M.K.K.
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