The Behaviour of Substituted Diaryl Nitroxyl Radicals and their Derivatives as Antifatigue Agents for Rubbers

Abstract

A variety of arylnitroxyl radicals and their precursors have been evaluated as antifatigue agents, antioxidants and antiozonants in natural rubber. Nitroxyl radicals and their derived hydroxyl amines were shown to be the active species during fatiguing and mechanistic studies using ESR have shown that these stable nitroxyl radicals are regenerated in a cyclicalmechanism, N-nitroso diaryl amines were shown to be highly effective antifatigue agents due in part to the formation and regeneration of the diaryl nitroxyl radicals. Diaryl nitrones were also shown to produce the corresponding nitroxyl radical during processing, although their antifatigue activity was low. However inclusion of a semi-hindered phenolic moiety in the molecule markedly improved activity...

Publication DOI: https://doi.org/10.48780/publications.aston.ac.uk.00011725
Divisions: College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry
Additional Information: Copyright © H.S. Dweik, 1983. H.S. Dweik asserts their moral right to be identified as the author of this thesis. This copy of the thesis has been supplied on condition that anyone who consults it is understood to recognise that its copyright rests with its author and that no quotation from the thesis and no information derived from it may be published without appropriate permission or acknowledgement. If you have discovered material in Aston Publications Explorer which is unlawful e.g. breaches copyright, (either yours or that of a third party) or any other law, including but not limited to those relating to patent, trademark, confidentiality, data protection, obscenity, defamation, libel, then please read our Takedown Policy and contact the service immediately.
Institution: Aston University
Uncontrolled Keywords: antiozonants,natural rubber,nitroxyl radicals,antifatigue agents,nitrones
Last Modified: 03 Apr 2025 14:07
Date Deposited: 12 Jan 2011 11:34
Completed Date: 1983
Authors: Dweik, Hasan Salah

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