Montoya, C.A., Gómez, C.F., Paninho, A.B., Nunes, A.V.M., Mahmudov, K.T., Najdanovic-Visak, V., Martins, L.M.D.R.S., Guedes Da Silva, M.F.C., Pombeiro, A.J.L. and Nunes Da Ponte, M. (2016). Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones. Journal of Catalysis, 335 , pp. 135-140.
Abstract
Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.
| Publication DOI: | https://doi.org/10.1016/j.jcat.2015.12.027 |
|---|---|
| Divisions: | College of Engineering & Physical Sciences > School of Infrastructure and Sustainable Engineering > Chemical Engineering & Applied Chemistry College of Engineering & Physical Sciences |
| Additional Information: | © 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| Publication ISSN: | 1090-2694 |
| Last Modified: | 15 Apr 2024 07:36 |
| Date Deposited: | 31 Oct 2019 13:19 |
| Full Text Link: |
http://www.scop ... tnerID=MN8TOARS |
| Related URLs: |
https://www.sci ... 004X?via%3Dihub
(Publisher URL) |
PURE Output Type: | Article |
| Published Date: | 2016-03-01 |
| Accepted Date: | 2015-12-30 |
| Authors: |
Montoya, C.A.
Gómez, C.F. Paninho, A.B. Nunes, A.V.M. Mahmudov, K.T. Najdanovic-Visak, V. ( 
0000-0002-1035-0982)
Martins, L.M.D.R.S. Guedes Da Silva, M.F.C. Pombeiro, A.J.L. Nunes Da Ponte, M. |
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