A magnetically-separable H3PW12O40@Fe3O4/EN-MIL-101 catalyst for the one-pot solventless synthesis of 2H-indazolo[2,1-b] phthalazine-triones

Hashemzadeh, Alireza, Amini, Mostafa M., Tayebee, Reza, Sadeghian, Atefeh, Durndell, Lee J., Isaacs, Mark A., Osatiashtiani, Amin, Parlett, Christopher M.A. and Lee, Adam F. (2017). A magnetically-separable H3PW12O40@Fe3O4/EN-MIL-101 catalyst for the one-pot solventless synthesis of 2H-indazolo[2,1-b] phthalazine-triones. Molecular Catalysis, 440 , pp. 96-106.

Abstract

A magnetic inorganic-organic catalyst, PTA@Fe3O4/EN-MIL-101 (EN = ethylenediamine, PTA = phosphotungstic acid) was fabricated and characterized by XRD, HRTEM, FESEM, UV–vis, TGA-DTA, FT-IR, XPS and porosimetry. PTA retained the parent Keggin structure upon dispersion throughout the amine-functionalized chromium terephthalate metal-organic framework, over which magnetic Fe3O4 nanoparticles were previously introduced. The resulting composite heterogeneous solid acid was an active catalyst for the one-pot synthesis of diverse 2H-indazolo[2,1-b] phthalazine-triones in good → excellent yields under mild, solventless condition, and offers facile separation and excellent recyclability.

Publication DOI: https://doi.org/10.1016/j.mcat.2017.07.010
Divisions: Engineering & Applied Sciences
Engineering & Applied Sciences > Chemical Engineering & Applied Chemistry
Engineering & Applied Sciences > European Bioenergy Research Institute (EBRI)
Additional Information: © 2017, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Uncontrolled Keywords: metal-organic framework,magnetic nanoparticles,heteropolyacid,phthalazine-trione,Catalysis,Process Chemistry and Technology,Physical and Theoretical Chemistry
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Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
Published Date: 2017-10
Authors: Hashemzadeh, Alireza
Amini, Mostafa M.
Tayebee, Reza
Sadeghian, Atefeh
Durndell, Lee J.
Isaacs, Mark A.
Osatiashtiani, Amin ( 0000-0003-1334-127X)
Parlett, Christopher M.A. ( 0000-0002-3651-7314)
Lee, Adam F. ( 0000-0002-2153-1391)

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