Niobic acid nanoparticle catalysts for the aqueous phase transformation of glucose and fructose to 5-hydroxymethylfurfural

Reche, Mariano Tapia, Osatiashtiani, Amin, Durndell, Lee J., Isaacs, Mark A., Silva, Ângela, Lee, Adam F. and Wilson, Karen (2016). Niobic acid nanoparticle catalysts for the aqueous phase transformation of glucose and fructose to 5-hydroxymethylfurfural. Catalysis Science and Technology, 6 (19), pp. 7334-7341.

Abstract

A family of bulk and SBA-15 supported peroxo niobic acid sols were prepared by peptisation of niobic acid precipitates with H2O2 as heterogeneous catalysts for aqueous phase glucose and fructose conversion to 5-hydroxymethylfurfural (5-HMF). Niobic acid nanoparticles possess a high density of Brønsted and Lewis acid sites, conferring good activity towards glucose and fructose conversion, albeit with modest 5-HMF yields under mild reaction conditions (100 °C). Thermally-induced niobia crystallisation suppresses solid acidity and activity. Nanoparticulate niobic acid dispersed over SBA-15 exhibits pure Brønsted acidity and an enhanced Turnover Frequency for fructose dehydration.

Publication DOI: https://doi.org/10.1039/c6cy01129b
Dataset DOI: https://doi.org/10.17036/b900b811-b0a9-405b-95b8-3437e41522e6
Divisions: Engineering & Applied Sciences > Chemical Engineering & Applied Chemistry
Engineering & Applied Sciences
Engineering & Applied Sciences > European Bioenergy Research Institute (EBRI)
Additional Information: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Funding: EPSRC (EP/K014706/1, EP/K000616/2, EP/K014676/1 and EP/K014749/1); and the Royal Society and British Council Global Innovation Initiative for GB3-Net. Electronic supplementary information (ESI) available: Additional structural and reactivity data. See DOI: 10.1039/c6cy01129b
Uncontrolled Keywords: Catalysis
Full Text Link: http://pubs.rsc ... 9B#!divAbstract
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
Published Date: 2016-10-07
Authors: Reche, Mariano Tapia
Osatiashtiani, Amin ( 0000-0003-1334-127X)
Durndell, Lee J.
Isaacs, Mark A.
Silva, Ângela
Lee, Adam F. ( 0000-0002-2153-1391)
Wilson, Karen ( 0000-0003-4873-708X)

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License: Creative Commons Attribution


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