Iron(III) spin crossover compounds


In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-β-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.

Publication DOI:
Divisions: Engineering & Applied Sciences > Aston Institute of Materials Research (AIMR)
Engineering & Applied Sciences > Chemical Engineering & Applied Chemistry
ISBN: 978-3-540-40394-4, 978-3-540-44981-2
Full Text Link: ... ngsbruggen2.pdf
Related URLs: http://link.spr ... /10.1007/b95409 (Publisher URL)
PURE Output Type: Chapter (peer-reviewed)
Published Date: 2004
Authors: van Koningsbruggen, Petra J. (ORCID Profile 0000-0001-9366-1913)
Maeda, Yonezo
Oshio, Hiroki

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