23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

Sutherland, Andrew J, Efremova, Olga, Shestopalov, Michael A., Vorotnikova, Natalya A., Vorotnikov, Yuri A., Mironov, Yuri V., Kitamura, Noboru, Novozhilov, Igor N., Syrokvashin, Mikhail, Nadolinny, Vladimir, Kuratieva, Natalia, Benoit, David, Walton, Rochard and Clarkson, Guy (2017). 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. Inorganic Chemistry ,

Abstract

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

Publication DOI: https://doi.org/10.1021/acs.inorgchem.7b02760
Divisions: Engineering & Applied Sciences > Chemical engineering & applied chemistry
Engineering & Applied Sciences > Polymer and advanced materials research group
Additional Information: This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher. Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1
Published Online Date: 2017-12-22
Authors: Sutherland, Andrew J ( 0000-0003-3651-1809)
Efremova, Olga
Shestopalov, Michael A.
Vorotnikova, Natalya A.
Vorotnikov, Yuri A.
Mironov, Yuri V.
Kitamura, Noboru
Novozhilov, Igor N.
Syrokvashin, Mikhail
Nadolinny, Vladimir
Kuratieva, Natalia
Benoit, David
Walton, Rochard
Clarkson, Guy

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