Temporary mirror symmetry breaking and chiral excursions in open and closed systems

Blanco, Celia, Stich, Michael and Hochberg, David (2011). Temporary mirror symmetry breaking and chiral excursions in open and closed systems. Chemical Physics Letters, 505 (4-6), pp. 140-147.

Abstract

The reversible Frank model is capable of amplifying the initial small statistical deviations from the idealized racemic composition. This temporary amplification can be interpreted as a chiral excursion in a dynamic phase space. It is well known that if the system is open to matter and energy exchange, a permanently chiral state can be reached asymptotically, while the final state is necessarily racemic if the system is closed. In this work, we combine phase space analysis, stability analysis and numerical simulations to study the initial chiral excursions and determine how they depend on whether the system is open, semi-open or closed.

Publication DOI: https://doi.org/10.1016/j.cplett.2011.02.032
Divisions: Engineering & Applied Sciences > Mathematics
Engineering & Applied Sciences > Systems analytics research institute (SARI)
Additional Information: © 2011, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Uncontrolled Keywords: Physical and Theoretical Chemistry,Physics and Astronomy(all)
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Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
Published Date: 2011-03-30
Authors: Blanco, Celia
Stich, Michael ( 0000-0001-8862-1044)
Hochberg, David

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