Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Efremova, Olga A., Brylev, Konstantin A., Vorotnikov, Yuri A., Vejsadová, Lucie, Shestopalov, Michael A., Chimonides, Gwen F., Mikes, Petr, Topham, Paul D., Kim, Sung-Jin, Kitamura, Noboru and Sutherland, Andrew J. (2016). Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. Journal of Materials Chemistry C, 4 (3), pp. 497-503.

Abstract

Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)6]2- (where OTs- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)2[{Mo6I8}(OTs)6], where dMDAEMA+ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

Publication DOI: https://doi.org/10.1039/c5tc03204k
Divisions: Engineering & Applied Sciences > Mathematics
Engineering & Applied Sciences > Chemical engineering & applied chemistry
Engineering & Applied Sciences > Polymer and advanced materials research group
Additional Information: This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Uncontrolled Keywords: Chemistry(all),Materials Chemistry
Full Text Link: http://pubs.rsc ... 4K#!divAbstract
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
Published Date: 2016-01-21
Authors: Efremova, Olga A.
Brylev, Konstantin A.
Vorotnikov, Yuri A.
Vejsadová, Lucie
Shestopalov, Michael A.
Chimonides, Gwen F.
Mikes, Petr
Topham, Paul D. ( 0000-0003-4152-6976)
Kim, Sung-Jin
Kitamura, Noboru
Sutherland, Andrew J. ( 0000-0003-3651-1809)

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Version: Accepted Version

License: Creative Commons Attribution Non-commercial


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