Cobalt promoted TiO2/GO for the photocatalytic degradation of oxytetracycline and Congo Red

Jo, Wan-Kuen, Kumar, Santosh, Isaacs, Mark A., Lee, Adam F. and Karthikeyan, S. (2017). Cobalt promoted TiO2/GO for the photocatalytic degradation of oxytetracycline and Congo Red. Applied Catalysis B: Environmental, 201 , pp. 159-168.

Abstract

A family of titania derived nanocomposites synthesized via sol-gel and hydrothermal routes exhibit excellent performance for the photocatalytic degradation of two important exemplar water pollutants, oxytetracycline and Congo Red. Low loadings of Co3O4 nanoparticles dispersed over the surfaces of anatase TiO2 confer visible light photoactivity for the aqueous phase decomposition of organics through the resulting heterojunction and reduced band gap. Subsequent modification of these Co3O4/TiO2 composites by trace amounts of graphene oxide nanosheets in the presence of a diamine linker further promotes both oxytetracycline and Congo Red photodegradation under simulated solar and visible irradiation, through a combination of enhanced photoresponse and consequent radical generation. Radical quenching and fluorescence experiments implicate holes and hydroxyl radicals as the respective primary and secondary active species responsible for oxidative photodegradation of pollutants.

Publication DOI: https://doi.org/10.1016/j.apcatb.2016.08.022
Dataset DOI: https://doi.org/10.17036/da75826a-bd7c-4ec2-9764-acdf0d658ade
Divisions: Engineering & Applied Sciences
Engineering & Applied Sciences > Chemical engineering & applied chemistry
Engineering & Applied Sciences > European Bioenergy Research Institute (EBRI)
Additional Information: © 2016 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license(http://creativecommons.org/licenses/by/4.0/).
Uncontrolled Keywords: photocatalysis,titania,cobalt,graphene oxide,nanocomposite,Catalysis,Environmental Science(all),Process Chemistry and Technology
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Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
Published Date: 2017-02
Authors: Jo, Wan-Kuen
Kumar, Santosh ( 0000-0002-1352-9945)
Isaacs, Mark A.
Lee, Adam F. ( 0000-0002-2153-1391)
Karthikeyan, S.

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