Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2

van Koningsbruggen, Petra J., Garcia, Yann, Bravic, Georges, Chasseau, Daniel and Kahn, Olivier Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2. Inorganica Chimica Acta, 326 (1), pp. 101-105.

Abstract

The synthesis and crystal structure of a novel one-dimensional Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4' coordinating bis(tetrazole) ligands in syn conformation. The Cu(II) ions are in a Jahn-Teller distorted octahedral environment (Cu(1)-N(11)=2.034(2) Å, Cu(1)-N(21)=2.041(2) Å and Cu(1)-N(31)=2.391(2) Å). The Cu⋯Cu separations are 7.420(3) Å.

Publication DOI: https://doi.org/10.1016/S0020-1693(01)00645-4
Divisions: Engineering & Applied Sciences > Chemical engineering & applied chemistry
Additional Information: Copyright 2007 Elsevier B.V., All rights reserved.
Uncontrolled Keywords: copper,chain structures,supramolecular chemistry
Authors: van Koningsbruggen, Petra J.
Garcia, Yann
Bravic, Georges
Chasseau, Daniel
Kahn, Olivier

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