A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

Efremova, O.A., Shestapalov, M.A., Chirtsova, N.A., Smolentsev, A.I., Mironov, Y.V., Kitamura, N., Brylev, K.A. and Sutherland, Andy (2014). A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials. Dalton Transactions, 43 (16), pp. 6021-6025.

Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I 8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex. This journal is

Publication DOI: https://doi.org/10.1039/c3dt53126k
Divisions: Engineering & Applied Sciences > Chemical engineering & applied chemistry
Engineering & Applied Sciences > Polymer and advanced materials research group
Additional Information: © The Royal Society of Chemistry 2014 Funding: Marie Curie Intra-European Fellowship (project “PolyMoRe”, no. 327440) and the Russian Foundation for Basic Research (Grants nos. 12-03- 31670 and 14-04-01816). Supplementary information available online on the journal pages.
Uncontrolled Keywords: Inorganic Chemistry
Full Text Link: https://hydra.h ... rces/hull:11414
Related URLs: http://www.scop ... tnerID=8YFLogxK (Scopus URL)
Published Date: 2014-04-28
Authors: Efremova, O.A.
Shestapalov, M.A.
Chirtsova, N.A.
Smolentsev, A.I.
Mironov, Y.V.
Kitamura, N.
Brylev, K.A.
Sutherland, Andy ( 0000-0003-3651-1809)

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