Effect of contact surfaces on the thermal and photoxidation of dehydrated castor oil

Doudin, Khalid, Al-Malaika, Sahar, Dole, H., Stirling, T. and Sharples, M. (2011). Effect of contact surfaces on the thermal and photoxidation of dehydrated castor oil. Polymer Degradation and Stability, 96 (4), pp. 438-454.


The effect of stainless steel, glass, zirconium and titanium enamel surfaces on the thermal and photooxidative toughening mechanism of dehydrated castor oil films deposited on these surfaces was investigated using different analytical and spectroscopic methods. The conjugated and non-conjugated double bonds were identified and quantified using both Raman spectroscopy and 1D and 2D NMR spectroscopy. The disappearance of the double bonds in thermally oxidised oil-on-surface films was shown to be concomitant with the formation of hydroperoxides (determined by iodometric titration). The type of the surface had a major effect on the rate of thermal oxidation of the oil, but all of the surfaces examined had resulted in a significantly higher rate of oxidation compared to that of the neat oil. The highest effect was exhibited by the stainless steel surface followed by zirconium enamel, titanium enamel and glass. The rate of thermal oxidation of the oil-on-steel surface (at 100 °C, based on peroxide values) was more than five times faster than that of oil-on-glass and more than 21 times faster than the neat oil when compared under similar thermal oxidative conditions. The rate of photooxidation at 60 °C of oil-on-steel films was found to be about one and half times faster than their rate of thermal oxidation at the same temperature. Results from absorbance reflectance infrared microscopy with line scans taken across the depth of thermally oxidised oil-on-steel films suggest that the thermal oxidative toughening mechanism of the oil occurs by two different reaction pathways with the film outermost layers, i.e. furthest away from the steel surface, oxidising through a traditional free radical oxidation process involving the formation of various oxygenated products formed from the decomposition of allylic hydroperoxides, whereas, in the deeper layers closer to the steel surface, crosslinking reactions predominate.

Publication DOI: https://doi.org/10.1016/j.polymdegradstab.2011.01.020
Divisions: Engineering & Applied Sciences > Chemical engineering & applied chemistry
Engineering & Applied Sciences > Polymer Processing and Performance Research Unit
Uncontrolled Keywords: Oxidation of oil deposited on surfaces,Thermal oxidation,Photooxidation,NMR spectroscopy,Polymers and Plastics,Materials Chemistry,Mechanics of Materials,Condensed Matter Physics
Full Text Link:
Related URLs: http://www.scopus.com/inward/record.url?scp=79952190427&partnerID=8YFLogxK (Scopus URL)
Published Date: 2011-04
Authors: Doudin, Khalid ( 0000-0003-3604-9861)
Al-Malaika, Sahar ( 0000-0002-1378-0603)
Dole, H.
Stirling, T.
Sharples, M.


Item under embargo

Export / Share Citation


Additional statistics for this record